What is the appilication of silicone oil CAS:63148-62-9
Dimethyl silicone oil (polydimethylsiloxane, PDMS) is a linear organosilicon polymer material with a siloxane bond (-Si-O-Si-) backbone and methyl (-CH₃) side groups. It possesses unique molecular structure and physicochemical properties, and is widely used in industries such as industrial manufacturing, medical care, and daily chemicals. The following is a detailed analysis of its core characteristics and application scenarios:
I. Core Characteristics and Chemical Structure
Chemical Structure
Its molecular formula is ((CH_3)_3SiO[(CH_3)_2SiO]_nSi(CH_3)_3). The siloxane bond (bond energy: 451 kJ/mol) endows it with high thermal stability. The outward arrangement of methyl side groups forms a helical structure, giving it low surface tension (20-22 mN/m) and excellent hydrophobicity.
Physicochemical Properties
Wide temperature stability: Can be used continuously at -50°C to 200°C, and withstand higher temperatures for short periods. It maintains fluidity even at low temperatures (e.g., the 5cSt grade remains liquid in liquid nitrogen at -196°C).
Adjustable viscosity: Viscosity ranges from 5 to 1,000,000 centistokes (cSt), from extremely thin liquid to semi-solid gel, which can be adjusted to meet the needs of different scenarios.
Physiological inertness: Non-toxic and non-irritating, compliant with FDA, EU and other pharmaceutical-grade standards, and can directly contact human tissues.
Chemical Stability
Resistant to corrosion by strong acids, strong bases, and inorganic salt solutions, and not prone to reaction with other substances, making it suitable for use in harsh environments.
II. In-depth Analysis of Industrial Applications
1. Medical and Life Sciences
Medical device lubrication: Low-viscosity (e.g., 5cSt) dimethyl silicone oil is used as a coating for surgical instruments, catheters, and syringes, which can reduce the friction coefficient to 0.012 and minimize tissue damage. For example, it is used as a lubricant for hair follicle extraction in hair transplant surgery to improve transplantation survival rate.
Drug carrier and excipient: Serves as an ointment base to enhance transdermal drug absorption, or as a lubricant for oral liquid bottle caps (complies with GB 9685-2016 food contact standard), reducing the opening torque by 30%-40%.
Defoamer and therapeutic application: The main component of oral gastrointestinal defoaming tablets and pulmonary edema defoaming aerosols, relieving symptoms through its defoaming effect.
2. Electronics and Power Industry
Precision electronic component protection: 5cSt ultra-low viscosity silicone oil penetrates micron-level gaps (e.g., <10μm gaps between chip packaging pads) to form an ultra-thin insulating film of 0.1-0.5μm, suitable for 5G radio frequency components and high-frequency transformers.
Insulation and cooling of power equipment: With a dielectric constant of 2.7-2.8, it is superior to most organic materials. Used as transformer oil and capacitor impregnating fluid, it can reduce power loss by 50% and extend equipment service life. For example, it replaces mineral oil in on-board transformers to improve flame retardancy and stability.
Extreme environment application: Under high vacuum (10⁻⁶ Pa) and space radiation, the evaporation loss of 5cSt silicone oil is <0.01%/1000h, which is used for lubrication of satellite antenna drive mechanisms.
3. Industrial and Mechanical Manufacturing
High-temperature lubrication and damping: Grades with 350-1000cSt are used for lubrication of high-temperature chains and gearboxes, maintaining stable lubrication performance above 200°C and reducing carbon deposition. High-viscosity (tens of thousands to hundreds of thousands of cSt) silicone oil is used as the medium for automotive engine torsional vibration absorption dampers to enhance durability.
Metal processing and mold release: 100-2000cSt silicone oil is used for mold release in metal stamping and injection molding, reducing friction coefficient and preventing adhesion, especially suitable for high-temperature molding phenolic resin and unsaturated polyester materials.
Sealing and protection: Coated on door, window, and curtain wall seals to form a hydrophobic film, improving weather resistance and sealing performance.
4. Daily Chemicals and Personal Care
Skin care products and cosmetics: 500-1000cSt silicone oil is used as a smoothing agent in creams and sunscreen sprays, forming a breathable protective film while providing a "zero-stickiness" skin feel (residual oil <0.2mg/cm²). Quick-drying sunscreen sprays (compounded with ethanol) form a film in 30 seconds, with a waterproof rating of IPX4.
Hair care products: 350-500cSt silicone oil is used in shampoos and hair masks to repair frizzy hair and resist static electricity, making hair smooth and easy to comb.
5. Food and Packaging
Food processing aids: Food-grade silicone oil (350-1000cSt) compliant with GB 30612-2014 is used as a baking release agent and chocolate coating anti-sticking agent, with a dosage ≤0.2g/kg and residual amount meeting FDA and EU regulations.
Packaging material protection: Coated on the inner wall of food packaging to prevent adhesion of contents and extend shelf life, such as lubrication of aluminum-plastic cap liners.
6. Innovative Applications in Special Fields
Aerospace: 5cSt silicone oil has a viscosity change coefficient <1.5 in the range of -60°C~120°C, serving as a damping medium for precision gyroscopes to ensure attitude control accuracy.
Microfluidics and biomedicine: PDMS elastomers are used to manufacture microfluidic chips, whose air permeability and biocompatibility support experiments such as cell culture and drug screening.
Cultural relic protection: Low-viscosity silicone oil penetrates into wood and paper to form a hydrophobic barrier, preventing moisture and oxidation damage.